Question {Neet 2015 PYQ} Redox Reaction

Question. Assuming complete ionization, same moles of which of the following compounds will require the least amount of acidified KMnO4 for complete oxidation?

A. FeC2O4
B. Fe(NO2)2
C. FeSO4
D. FeSO3
Solution. Option C is Correct. MnO4 − ⟶ Mn2+ ; Change in oxidation no. = 5 In option, i. Fe2+ ⟶ Fe3+ Change in oxidation no. = 1 ii. Fe2+ ⟶ Fe3+ Change in oxidation no. = 1 SO3 2− ⟶ SO4 2− Change in oxidation no. = 2 = 1 + 2 = 3 iii. Fe2+ ⟶ Fe3+ Change in oxidation no. = 1 C2O4 2− ⟶ 2CO2 Change in oxidation no. = 2 = 1 + 2 = 3 iv. Fe2+ ⟶ Fe3+ Change in oxidation no. = 1 2NO2 − ⟶ 2NO3 − Change in oxidation no. = 4 = 1 + 4 = 5

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